The mean free path of a particle is the average distance covered by a particle between subsequent
impacts. If the molecules have diameter d, then the effective cross-section for the collision can be
modeled by using a circle of diameter 2d to represent a molecule’s effective collision area while
treating the target molecules as point masses.
Now, the circle would sweep out the volume within time t and the number of collisions can be
estimated from the number of gas molecules that were in that volume. Then the mean free path is
the length of the path divided by the number of collisions. The length of the path is given as:
If the number of molecules per unit volume = nvv and volume of interaction = πd2vt, then the mean free path can be estimated as: