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Diffraction



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Physics    Waves and Optics   Diffraction

Dispersion and Resolving Power

 

                    The diffraction grating is most useful for measuring wavelengths accurately. Like the prism, the diffraction grating can be used to disperse a spectrum into its wavelength components. Of the two devices, the grating is the more precise if one wants to distinguish two closely spaced wavelengths. For two nearly equal wavelengths λ1 and λ2 between which a diffraction grating can just barely distinguish, the resolving power R of the grating is defined as

where and Thus, a grating that has a high resolving power can distinguish small differences in wavelength. If N lines of the grating are illuminated, it can be shown that the resolving power in the mth-order diffraction is

                                                 

X-ray Diffraction

                 X-rays are electromagnetic waves of very short wavelength (of the order of 0.1 nm). It would be impossible to construct a grating having such a small spacing by the cutting process. However, the atomic spacing in a solid is known to be about 0.1 nm. In 1913, Max von Laue (1879–1960) suggested that the regular array of atoms in a crystal could act as a three-dimensional diffraction grating for X-rays. Subsequent experiments confirmed this prediction. The diffraction patterns are complex because of the three-dimensional nature of the crystal. Nevertheless, X-ray diffraction has proved to be an invaluable technique for elucidating crystalline structures and for understanding the structure of matter experimental arrangement for observing x-ray diffraction from a crystal.

 

                                    

 

A collimated beam of x-rays is incident on a crystal. The diffracted beams are very intense in certain directions, corresponding to constructive interference from waves reflected from layers of atoms in the crystal. The diffracted beams can be detected by a photographic film, and they form an array of spots known as a Laue pattern. One can deduce the crystalline structure by analyzing the positions and intensities of the various spots in the pattern.




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